27 February 2013

Stretchable Lithium Ion Battery Developed For Use In Implantable Electronic Biodevices

A lithium ion battery that can be stretched, bent, and twisted has been developed. These batteries can be used in implantable biological devices where size and shape of current batteries would be an issue in its performance and application.

Lithium ion batteries are the most popular type of batteries used for electronic devices. Li-ion batteries can be comprised of smaller units called cells.

Electrical current reaches the cells by conductive surfaces usually made up of aluminum on one side and copper on the other side. The battery is made up of a positive and negative electrode called the cathode and the anode.

The positive electrode (cathode) is made of lithium metal oxide. On the other side of the battery lies the negative electrode (anode) and is made up of graphite.

In the middle of the cathode and anode is the electrolyte. This allows the lithium ions carrying the electrical charge to flow freely from the anode to the cathode. It also allows transport of ions from the cathode to the anode during the charging process.

Li-ion batteries are popular because of their proven track record in long battery life and battery performance due to their energy density slow loss of charge when not in use.

Stretchable Lithium Ion Battery Developed

Northwestern University's Yonggang Huang and the University of Illinois' John A. Rogers are the first to demonstrate a stretchable lithium-ion battery -- a flexible device capable of powering their innovative stretchable electronics.

No longer needing to be connected by a cord to an electrical outlet, the stretchable electronic devices now could be used anywhere, including inside the human body. The implantable electronics could monitor anything from brain waves to heart activity, succeeding where flat, rigid batteries would fail.

Huang and Rogers have demonstrated a battery that continues to work -- powering a commercial light-emitting diode (LED) -- even when stretched, folded, twisted and mounted on a human elbow. The battery can work for eight to nine hours before it needs recharging, which can be done wirelessly.

The new battery enables true integration of electronics and power into a small, stretchable package. Details will be published Feb. 26 by the online journal Nature Communications.

"We start with a lot of battery components side by side in a very small space, and we connect them with tightly packed, long wavy lines," said Huang, a corresponding author of the paper. "These wires provide the flexibility. When we stretch the battery, the wavy interconnecting lines unfurl, much like yarn unspooling. And we can stretch the device a great deal and still have a working battery."

Video: Lithium-ion batteries: How do they work?

Huang led the portion of the research focused on theory, design and modeling. He is the Joseph Cummings Professor of Civil and Environmental Engineering and Mechanical Engineering at Northwestern's McCormick School of Engineering and Applied Science.

The power and voltage of the stretchable battery are similar to a conventional lithium-ion battery of the same size, but the flexible battery can stretch up to 300 percent of its original size and still function.

Rogers, also a corresponding author of the paper, led the group that worked on the experimental and fabrication work of the stretchable battery. He is the Swanlund Chair at the University of Illinois at Urbana-Champaign.

Huang and Rogers have been working together for the last six years on stretchable electronics, and designing a cordless power supply has been a major challenge. Now they have solved the problem with their clever "space filling technique," which delivers a small, high-powered battery.

For their stretchable electronic circuits, the two developed "pop-up" technology that allows circuits to bend, stretch and twist. They created an array of tiny circuit elements connected by metal wire "pop-up bridges." When the array is stretched, the wires -- not the rigid circuits -- pop up.

This approach works for circuits but not for a stretchable battery. A lot of space is needed in between components for the "pop-up" interconnect to work. Circuits can be spaced out enough in an array, but battery components must be packed tightly to produce a powerful but small battery. There is not enough space between battery components for the "pop-up" technology to work.

Huang's design solution is to use metal wire interconnects that are long, wavy lines, filling the small space between battery components. (The power travels through the interconnects.)

The unique mechanism is a "spring within a spring": The line connecting the components is a large "S" shape and within that "S" are many smaller "S's." When the battery is stretched, the large "S" first stretches out and disappears, leaving a line of small squiggles. The stretching continues, with the small squiggles disappearing as the interconnect between electrodes becomes taut.

"We call this ordered unraveling," Huang said. "And this is how we can produce a battery that stretches up to 300 percent of its original size."

The stretching process is reversible, and the battery can be recharged wirelessly. The battery's design allows for the integration of stretchable, inductive coils to enable charging through an external source but without the need for a physical connection.

Huang, Rogers and their teams found the battery capable of 20 cycles of recharging with little loss in capacity. The system they report in the paper consists of a square array of 100 electrode disks, electrically connected in parallel.


Northwestern University
Nature Communications
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