Thermodynamics
Thermodynamics is the branch of science that studies the relationships of heat, work, energy, and pressure.
In thermodynamics, it studies the interaction in relation to two kinds of systems: an isolated system and an open system. In an isolated system, material and energy of an object cannot exchange with its environment. In an open system, material and energy can exchange with its environment. Both this systems are precisely defined regions or spaces under study. Everything else outside the system is known as the surroundings.
A boundary separates the system and the surroundings. This is simply a surface surrounding the system or volume of interest. Anything that passes across the boundary that effects a change in the internal energy needs to be accounted for in the energy balance equation.
Laws of Thermodynamics
There are four laws that govern the behavior of energy and the passing of energy in thermodynamics. These are:
The Zeroth law: When 2 systems are in thermal equilibrium with a third system, these 2 systems are in thermal equilibrium with each other. Simply, if 2 objects have the same temperature with one other object, these two objects have the same temperature with each other.
- There is no heat flow between objects of the same temperature.
The 1st Law of Thermodynamics: This is also known as the law of conservation of energy. It states that the total energy in an isolated system never changes.
- Energy cannot be created or destroyed, it can only be transferred.
The 2nd Law of Thermodynamics: This law states that the entropy of an isolated system always increases or remains constant over time. Entropy as used in this law can be defined as disorder. An example of the 2nd law in action are ubiquitous in nature; ice melting, fires burning down, a battery running out of electrical charge, etc.- The 2nd law is the reason why heat always transfers from a relatively higher temperature to an object that is lower.
The 3rd Law of Thermodynamics: The 3rd law states that it is impossible to cool an object down to a temperature of absolute zero. It can also be stated in terms of heat; it is impossible to remove all the heat from a physical system.
- The lowest possible limit on temperature is absolute zero. Temperature can never be lower than this in the whole universe. In quantitative terms, absolute zero can be measured as 0 Kelvin (K), -273.15 Celsius (C), or -459.67 Fahrenheit(F),
- In 2003, MIT Researchers achieved the lowest temperature which is .45 nK (nano kelvin) or 4.5 x 10-10 K or 0.00000000045 K
These laws dictate how heat, energy, and pressure behave within a thermodynamic system.
Heat Transfer
As with the laws of thermodynamics, the transfer of heat between one object to another is defined by these. Heat is transferred from one object to another through one of four fundamental modes:
- Conduction or diffusion: The transfer of energy between objects that are in physical contact
- Convection: The transfer of energy between an object and its environment, due to fluid motion
- Radiation: The transfer of energy to or from a body by means of the emission or absorption of electromagnetic radiation
- Advection: The transfer of energy from one location to another as a side effect of physically moving an object containing that energy
Better surfaces could help dissipate heat
Cooling systems that use a liquid that changes phase — such as water boiling on a surface — can play an important part in many developing technologies, including advanced microchips and concentrated solar-power systems. But understanding exactly how such systems work, and what kinds of surfaces maximize the transfer of heat, has remained a challenging problem. Now, researchers at MIT have found that relatively simple, microscale roughening of a surface can dramatically enhance its transfer of heat. Such an approach could be far less complex and more durable than approaches that enhance heat transfer through smaller patterning in the nanometer (billionths of a meter) range.
The new research also provides a theoretical framework for analyzing the behavior of such systems, pointing the way to even greater improvements. The work was published this month in the journal Applied Physics Letters, in a paper co-authored by graduate student Kuang-Han Chu, postdoc Ryan Enright and Evelyn Wang, an associate professor of mechanical engineering.